Analisis Sifat Kemagnetan Nanomaterial Magnetik ZnFe2O4 Berbahan Dasar Pasir Besi Dengan Metode Kopresipitasi
Abstract
Iron sand is a natural resource rich in iron oxide compounds such as Fe?O?, ?-Fe?O?, and ?-Fe?O?, which have the potential to be developed into functional materials, particularly magnetic nanoparticles. This study aims to analyze the magnetic properties of ZnFe?O? nanomaterials synthesized from iron sand using the coprecipitation method. The synthesis was carried out by dissolving iron sand in HCl, mixing with a ZnCl? solution and titrating with NH?OH until a dark brown precipitate was formed. The precipitate was heated at 200?°C for 2 hours. Characterization was conducted using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Vibrating Sample Magnetometry (VSM). XRD results confirmed the presence of ZnFe?O? phase by JCPDS No. 22-1012, with a crystallite size of 24.9 nm and a lattice parameter of 8.28 Å. SEM images revealed non-uniform particle morphology and agglomeration. VSM results showed a remanent magnetization (Mr) of 0.0016 emu, coercivity (Hc) of 314 Oe, and saturation magnetization (Ms) of 1.540 emu. Based on these results, the material exhibits soft ferromagnetic behavior consistent with the spinel structure of ZnFe?O?.
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References
[1] Nyangiwe, NN. 2025. Aplications of density functional theory and machine learning in nanomaterials : A review. Next Materials. vol 8. pp 1 -21.
[2] Nengsih S 2021 Review literatur: Sintesis pasir besi menjadi nanomaterial magnetit melalui penerapan metode kopresipitasi. Amina: J. Ar-Raniry 3(3), 112–122.
[3] Amiri M, Salavati-Niasari M and Akbari A 2019 Magnetic nanocarriers: Evolution of spinel ferrites for medical applications. Adv. Colloid Interface Sci. 265, 29–44.
[4] Bakri AI 2020 Sintesis dan karakterisasi senyawa hematite bermaterial dasar pasir besi Bonto Kanang Takalar Kabupaten Takalar. J. Ilmu Fisika: Teori dan Aplikasinya 2(2), 55–58.
[5] Silvia L and Zainuri M 2020 Analisis silika (SiO₂) hasil kopresipitasi berbasis material alam menggunakan uji XRF dan XRD. J. Fisika dan Aplikasinya 16, 12–17.
[6] Rahmayanti M 2020 Sintesis dan karakterisasi magnetit (Fe₃O₄): Studi komparasi metode konvensional dan metode sonokimia. Al-Ulum Sains dan Teknologi 6(1), 26–31.
[7] Hasanah I, Rohman L and Supripyanto E 2020 Kurva histerisis material feromagnetik Co₀.₈Pt₀.₂ pada tiga daerah domain. J. Pendidikan Fisika dan Keilmuan (JPFK) 6(1), 47–54.
[8] Hu M, Butt HJ, Landfester K, Bannwarth MB, Wooh S and Thérien-Aubin H 2019 Shaping the assembly of superparamagnetic nanoparticles. ACS Nano 13, 3015–3022.
[9] Zhang J, Song JM, Niu HL, Mao CJ, Zhang SY and Shen YH 2015 ZnFe₂O₄ nanoparticles: Synthesis, characterization, and enhanced sensing property for acetone. Sens. Actuators B Chem. 221, 55–62.
[10] Hayati R and Astuti A 2015 Sintesis nanomaterial silika dari pasir pantai Purus Padang Sumatra Barat dengan metode kopresipitasi. J. Fisika Unand 4(3), 282–287.
[11] Gunanto YE 2018 High purity Fe₃O₄ from local iron sand extraction. J. Phys.: Conf. Ser. 1011, 012014.
[12] Abdullah JAA, Jiménez-Rosado M, Guerrero A and Romero A 2023 Effect of calcination temperature and time on the synthesis of iron oxide nanoparticles: Green vs. chemical method. Materials 16(5), 1–18.
[13] Nurpriyanti I, Mastuki M and Sulistyorini E 2024 Synthesis and characterization of ZnFe₂O₄ based on iron sand as a magnetic material. Phys. Mech. New Mater. Their Appl. Nova Science Publishers, USA.
[14] Mekuye B and Abera B 2023 Nanomaterials: An overview of synthesis, classification, characterization, and applications. Nano Select 4, 486–501.
[15] Gestarila C and Puryanti D 2020 Sintesis nanomaterial zink ferit (ZnFe₂O₄) dengan metode kopresipitasi dan karakterisasi struktur kristalnya. J. Fisika Unand 9(3), 299–303.
[16] Restelli S, Albini B, Bonomi S, Bini M, Mozzati MC and Galinetto P 2023 Raman study of the laser-induced decomposition of ZnFe₂O₄ nanoparticles. Mater. Today Commun. 35, 106405.
[17] Puspitasari P, Rizkia UA, Sukarni S, Permanasari AA, Taufiq A and Putra ABNR 2021 Effects of various sintering conditions on the structural and magnetic properties of zinc ferrite (ZnFe₂O₄). Mater. Res. 24(1), 1–9.
[18] Andhare DD, Jadhav SA, Khedkar MV, Somvanshi SB, More SD and Jadhav KM 2020 Structural and chemical properties of ZnFe₂O₄ nanoparticles synthesised by chemical co-precipitation technique. J. Phys.: Conf. Ser. 1644, 012014.
[19] Huerta-Aguilar CA, Diaz-Puerto ZJ, Tecuapa-Flores ED and Thangarasu P 2022 Crystal plane impact of ZnFe₂O₄-Ag nanoparticles influencing photocatalytical and antibacterial properties: Experimental and theoretical studies. ACS Omega 7(38), 33985–34001.
[20] Kiswanto H 2020 Analisis perumaterial struktur kristal dan distribusi kation cobalt ferrite akibat substitusi zinc. J. Ilmu dan Inovasi Fisika (JIIF) 4(2), 155–163.
[21] Husain S, Yusup M, Haryanti NH, Suryajaya S, Saukani M, Rodiansono A and Riyanto A 2020 Characteristics of zinc ferrite nanoparticles (ZnFe₂O₄) from natural iron ore. IOP Conf. Ser.: Earth Environ. Sci. 758, 012001.
[22] Hall CA, Ferrer P, Grinter DC, Kumar S, da Silva I, Robio-Zuazo J, Bencok P, De Groot F, Held G and Grau-Crespo R 2024 Spinel ferrites MFe₂O₄ (M = Co, Cu, Zn) for photocatalysis: Theoretical and experimental insights. J. Mater. Chem. A 12, 29645–29656.
[2] Nengsih S 2021 Review literatur: Sintesis pasir besi menjadi nanomaterial magnetit melalui penerapan metode kopresipitasi. Amina: J. Ar-Raniry 3(3), 112–122.
[3] Amiri M, Salavati-Niasari M and Akbari A 2019 Magnetic nanocarriers: Evolution of spinel ferrites for medical applications. Adv. Colloid Interface Sci. 265, 29–44.
[4] Bakri AI 2020 Sintesis dan karakterisasi senyawa hematite bermaterial dasar pasir besi Bonto Kanang Takalar Kabupaten Takalar. J. Ilmu Fisika: Teori dan Aplikasinya 2(2), 55–58.
[5] Silvia L and Zainuri M 2020 Analisis silika (SiO₂) hasil kopresipitasi berbasis material alam menggunakan uji XRF dan XRD. J. Fisika dan Aplikasinya 16, 12–17.
[6] Rahmayanti M 2020 Sintesis dan karakterisasi magnetit (Fe₃O₄): Studi komparasi metode konvensional dan metode sonokimia. Al-Ulum Sains dan Teknologi 6(1), 26–31.
[7] Hasanah I, Rohman L and Supripyanto E 2020 Kurva histerisis material feromagnetik Co₀.₈Pt₀.₂ pada tiga daerah domain. J. Pendidikan Fisika dan Keilmuan (JPFK) 6(1), 47–54.
[8] Hu M, Butt HJ, Landfester K, Bannwarth MB, Wooh S and Thérien-Aubin H 2019 Shaping the assembly of superparamagnetic nanoparticles. ACS Nano 13, 3015–3022.
[9] Zhang J, Song JM, Niu HL, Mao CJ, Zhang SY and Shen YH 2015 ZnFe₂O₄ nanoparticles: Synthesis, characterization, and enhanced sensing property for acetone. Sens. Actuators B Chem. 221, 55–62.
[10] Hayati R and Astuti A 2015 Sintesis nanomaterial silika dari pasir pantai Purus Padang Sumatra Barat dengan metode kopresipitasi. J. Fisika Unand 4(3), 282–287.
[11] Gunanto YE 2018 High purity Fe₃O₄ from local iron sand extraction. J. Phys.: Conf. Ser. 1011, 012014.
[12] Abdullah JAA, Jiménez-Rosado M, Guerrero A and Romero A 2023 Effect of calcination temperature and time on the synthesis of iron oxide nanoparticles: Green vs. chemical method. Materials 16(5), 1–18.
[13] Nurpriyanti I, Mastuki M and Sulistyorini E 2024 Synthesis and characterization of ZnFe₂O₄ based on iron sand as a magnetic material. Phys. Mech. New Mater. Their Appl. Nova Science Publishers, USA.
[14] Mekuye B and Abera B 2023 Nanomaterials: An overview of synthesis, classification, characterization, and applications. Nano Select 4, 486–501.
[15] Gestarila C and Puryanti D 2020 Sintesis nanomaterial zink ferit (ZnFe₂O₄) dengan metode kopresipitasi dan karakterisasi struktur kristalnya. J. Fisika Unand 9(3), 299–303.
[16] Restelli S, Albini B, Bonomi S, Bini M, Mozzati MC and Galinetto P 2023 Raman study of the laser-induced decomposition of ZnFe₂O₄ nanoparticles. Mater. Today Commun. 35, 106405.
[17] Puspitasari P, Rizkia UA, Sukarni S, Permanasari AA, Taufiq A and Putra ABNR 2021 Effects of various sintering conditions on the structural and magnetic properties of zinc ferrite (ZnFe₂O₄). Mater. Res. 24(1), 1–9.
[18] Andhare DD, Jadhav SA, Khedkar MV, Somvanshi SB, More SD and Jadhav KM 2020 Structural and chemical properties of ZnFe₂O₄ nanoparticles synthesised by chemical co-precipitation technique. J. Phys.: Conf. Ser. 1644, 012014.
[19] Huerta-Aguilar CA, Diaz-Puerto ZJ, Tecuapa-Flores ED and Thangarasu P 2022 Crystal plane impact of ZnFe₂O₄-Ag nanoparticles influencing photocatalytical and antibacterial properties: Experimental and theoretical studies. ACS Omega 7(38), 33985–34001.
[20] Kiswanto H 2020 Analisis perumaterial struktur kristal dan distribusi kation cobalt ferrite akibat substitusi zinc. J. Ilmu dan Inovasi Fisika (JIIF) 4(2), 155–163.
[21] Husain S, Yusup M, Haryanti NH, Suryajaya S, Saukani M, Rodiansono A and Riyanto A 2020 Characteristics of zinc ferrite nanoparticles (ZnFe₂O₄) from natural iron ore. IOP Conf. Ser.: Earth Environ. Sci. 758, 012001.
[22] Hall CA, Ferrer P, Grinter DC, Kumar S, da Silva I, Robio-Zuazo J, Bencok P, De Groot F, Held G and Grau-Crespo R 2024 Spinel ferrites MFe₂O₄ (M = Co, Cu, Zn) for photocatalysis: Theoretical and experimental insights. J. Mater. Chem. A 12, 29645–29656.
Published
2025-05-28
How to Cite
NURPRIYANTI, Indah; SULISTYORINI, Elisa; MASTUKI, Mastuki.
Analisis Sifat Kemagnetan Nanomaterial Magnetik ZnFe2O4 Berbahan Dasar Pasir Besi Dengan Metode Kopresipitasi.
BULETIN FISIKA, [S.l.], v. 26, n. 1, p. 105 – 111, may 2025.
ISSN 2580-9733.
Available at: <http://103.29.196.112/index.php/buletinfisika/article/view/127551>. Date accessed: 16 dec. 2025.
doi: https://doi.org/10.24843/BF.2025.v26.i01.p13.
Section
Articles
